Participant from UHA
photo of SAMET_DALGA , description text of his Synthesis of photoacid base LED sensitive photoinitiators

PROJECT OBJECTIVES

Development of LED sensitive photoinitiators for ionic processes (i.e., PhotoBase (PBG) and PhotoAcid (PAG) Generators) adapted to monochromatic light sources, in view of additive manufacturing applications.

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Characterization of their efficiency and its improvement by combination with redox additives in photocyclic initiating systems.

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Development of sustainable formulations for ionically photocured composites containing cellulose fillers (academic secondment).

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Obtaining of at least one photoinitiator that allows photopolymerisation processes more sustainable than the selected benchmark and has comparable performances.

EXPECTED RESULTS

Protocols for the synthesis of PBG and PAG and their photochemical study under LED irradiation.

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Optimization of their photochemical efficiency in photocurable formulations.

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Setting of an appropriate sustainability metrics for photoinitiators, and sustainability assessment of the newly synthesised photoinitiators.

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Trained researcher expert on the synthesis and characterisation of innovative ionic photoinitiators and on photoinduced processes suitable for coating materials, acquired also during secondments.

PLANNED SECONDMENTS

HOST 1

POLITO (IT), supervisor: R. Bongiovanni, timing: month 35, length: 6 months. Purpose: development of cellulose-based ionically photocured materials.

HOST 2

KAYALAR KİMYA (TR), supervisor: E. Erguven, timing: month 29, length: 3 months. Purpose: acquire knowledge on the preparation of coatings.

*Enrolment in Doctoral degree: at UHA. Prof. X. Allonas will act as supervisor and Prof. C. Croutxé-Barghorn as co-supervisor

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This project has received funding from the EU’s Horizon 2021 programme under the Marie Skłodowska-Curie Doctoral Networks (MSCA-DN) grant agreement No 101073432.
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